I have heard some pretty weird stuff from shops, and I'm not sure I believe this.
Alternators don't have "residual magnetism". At least not as a design feature. The field magnet (the part that rotates) is supposed to be magnetized by the field coil, which is driven through the brushes. Without any field current, there may or may not be some output on the windings, depending on whether there is indeed "residual magnetism" in the iron. But it's not guaranteed by any means, and you shouldn't need it anyway. The field current is supposed to come from the battery.
If you have an external regulator, then the Field terminal should go hot as soon as you turn on the ignition switch. This provides field from the battery.
If you have an internal regulator, then the power for the regulator, and thus the field, comes from the hot terminal. If this is connected to the battery, there is no problem.
What happened to me was that each of my single-terminal alternators was driving several batteries through a diode splitter. Current could not go backwards from the battery through the diode to the alternator, so there was no power to the alternator to run the field. The alternators did not start.
This was particularly distressing since the tach drive is from the alternator, since I have no points, and so I would be starting the engines and not able to see the rpms.
At some rpm, around 1500 or so, the alternators would "light up" and I would get both charge and a reading of engine revs. After that they would work. This, of course, was caused by the "residual magnetism" in the iron that created enough output to provide field, after which all was OK.
But this is not guaranteed, and in fact one alternator had better iron than the other and therefore started at a much higher engine rpm.
The cure is to provide field power from the ignition. But, if you just hook the ignition to the alternator output, it will try to charge the battery through that tiny wire. A diode lets the field current flow from the battery, but stops any current from the alternator to the ignition and battery.
1975 32' Flybridge Sedan, twin Perkins 6-354 diesels, 1:1.53 velvetdrives, 16 X 19 props. Merritt Island, Florida