You betcha. The drill is to leave the battery switch on "1" after the engine is started, and wait for the start battery to come back up to full voltage. Then, switch to "both" to put current into the house battery. The switch must be wired so that it does not leave the alternator disconnected from a battery at the same time that it has field voltage, because the resulting huge voltage spike is sure to damage something. Many battery switches turn off the field for you, watch out for Perko!
I used to have enthusiastic crew who would watch the voltmeter and then switch over at the correct time. Now that she is 16 and has reached her "whatever!" years, I would have to do it myself. So I installed a bunch of diodes to direct the alternator current to the appropriate battery automatically.
This works, but there is a voltage drop across the diodes, around 0.7 Volt, and this fools the regulator. I get away with it because my alternators put out 14.7 Volts but my AGM batteries will charge properly at 14 Volts. Still, at 70 Amps of charge, there is a loss of around 50 Watts in the diode. The practical effect is that, without the diode, the alternator will put out more current. Let's face it, diode isolators are so last decade.
With the combiners, the device waits for the voltage on the charged battery to come up, then switches in the house battery, all automatically. No more "I forgots". And the circuit is much simpler.
1975 32' Flybridge Sedan, twin Perkins 6-354 diesels, 1:1.53 velvetdrives, 16 X 19 props. Merritt Island, Florida